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(6 replies, posted in Music theory)

In the key of A minor you might be able to use both the E major and the E minor chords.  Harmonizing the A natural minor scale gets a Emin, and harmonizing the A harmonic minor gets the E chord.  I know this isn't what you asked about but I got to thinking about it when I read your question incorrectly.  It might be useful to be able to find a theoretical reason why E-Emin might work in a song.  I'm thinking anytime I see a major to minor chord switch I'll check and see if the chords in question are the V chords of the harmonic and natural minor scales.

Thinking about the harmonized major scale, the dominant chord would normally be the V7 chord.  In the key of G it would be D7 (D, F#, A, C).  In the song you mention it looks like the D7 resolves to the chord that is a fifth below it, the G chord.  The B7 (B D# F# A) contains a tritone between the D# and A.  Typically the D# would resolve up to E and the A would resolve down to G#, just as the V7 chord did.  The chord that comes after the B7 is C (C E G).  It contains the E that the D# is pulling towards, but not the G#.  This ought to leave that section of the song with a bit of unresolved tension, a feeling of mobility, which in this case makes sense because the truer, stronger resolution comes at the end when the D7 comes back to G. 

I think.  smile